Published on June 16th, 2013 | by Nicholas Brown
All-Solid Lithium-Sulfur Battery Stores 4x As Much As Li-ion
Lithium-sulfur (Li-S) batteries have been under development for years, and have already demonstrated the ability to store 400 Wh per kg of batteries. However, this time, there is an all-solid lithium-sulfur battery that could do even better. Will it last longer than previous lithium-sulfur batteries?
Lithium-sulfur batteries have been stated to last “few tens of cycles” before malfunctioning, according to a scholar at Stanford University, Johanna Nelson. This was said to be due the loss of sulfur in the cathode.
“The cycle life of lithium-sulfur batteries is very short. Typically, after a few tens of cycles the battery will die, so it isn’t viable for electric vehicles, which require many thousands of cycles over a 10- or 20-year lifetime.”
“Based on previous experiments, we expected sulfur particles to completely disappear from the cathode when the battery discharges,” said Nelson, the lead author of the JACS study. “Instead, we saw only negligible changes in the size of the particles, the exact opposite of what earlier studies found.”
This is another reminder to stay as objective as possible. Sometimes researchers come to incorrect conclusions and then base future research and designs on those conclusions.
This new solid battery (not to be confused with solid-state batteries) was able to survive 300 cycles without malfunctioning, and it still achieves four times the energy density of conventional lithium-ion batteries.
Its success is partially attributed to reduced “sulfur dissolution,” because the electrolyte is solid. The researchers developed this battery’s electrolyte and cathode with sulfur that was obtained as a byproduct of oil extraction, which helps keep the cost of it down.
Using byproducts instead of mining them also tends to be the most sustainable way to go.
Another heartwarming fact is that sulfur stores more energy than the other, less-sustainable transition metals used in lithium-ion battery cathodes.